Von Braun (BrCN) Reaction on Solasodine
نویسندگان
چکیده
von Braun Cyanogen Bromide Reaction, Solasodine, 13C NMR Solasodine on reaction with BrCN yielded two isomeric cyanamides in a ratio of 3:1, which have been characterised as C-22 configurational isomers, N-cyanosolasodine (22 R, 25 R) I IA and N-cyanosolasodine (22 S, 25 Rj II B on the basis of HI and *3C NMR studies. The same reaction with piperidine, yielded its cyanamide, the 13C NMR of which is also reported.
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